Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes
نویسندگان
چکیده
منابع مشابه
Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds.
Dehydrogenation of Me(2)NH·BH(3) (1) by group 4 metallocene alkyne complexes of the type Cp(2)M(L)(η(2)-Me(3)SiC(2)SiMe(3)) [Cp = η(5)-cyclopentadienyl; M = Ti, no L (2Ti); M = Zr, L = pyridine (2Zr)] and group 4 metal amido complexes of the type M(NMe(2))(4) [M = Ti (8Ti), Zr (8Zr)] is presented.
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A study of the dehydrogenation of dimethylamine borane using different titanocene(III) complexes with 2-phosphinoaryloxide ligands is presented. Complexes Cp2Ti(κ(2)-O, P-O-C6H4-PR2) (3a: R = i-Pr, 3b: R = Ph) (Cp = η(5)-cyclopentadienyl) and Cp*2Ti(κ(1)-O-O-C6H4-PR2) (5a: R = i-Pr, 5b: R = Ph) (Cp* = η(5)-pentamethylcyclopentadienyl) were prepared by reactions of the 2-phosphinophenol ligand w...
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2018
ISSN: 1359-7345,1364-548X
DOI: 10.1039/c7cc08385h